| Pick | Overall | Team | Player | Position | School | State |
| 1 | 602 | Pittsburgh Pirates | Trea Turner | SS | Park Vista HS, Lake Worth, Fla. | Fla. |
| 2 | 603 | Seattle Mariners | Dillon Hazlett | 2B | Emporia State (Kan.) | Kan. |
| 3 | 604 | Arizona Diamondbacks | Tommy Williams | SS | Palm Beach Gardens (Fla.) HS | Fla. |
| 4 | 605 | Baltimore Orioles | Marc Wik | OF | Chabot (Calif.) JC | Calif. |
| 5 | 606 | Kansas City Royals | Terrance Gore | OF | Gulf Coast (Fla.) CC | Fla. |
| 6 | 607 | Washington Nationals | Josh Laxer | RHP | Madison (Miss.) Central HS | Miss. |
| 7 | 608 | Cleveland Indians | Dillon Peters | LHP | Cathedral HS, Indianapolis | Ind. |
| 8 | 609 | Chicago Cubs | Ben Klafczynski | OF | Kent State | Ohio |
| 9 | 610 | Houston Astros | Matt Duffy | 3B | Tennessee | Tenn. |
| 10 | 611 | Milwaukee Brewers | Brandon Williamson | RHP | Dallas Baptist | Texas |
| 11 | 612 | New York Mets | Mason Robbins | OF | George County HS, Lucedale, Miss. | Miss. |
| 12 | 613 | Florida Marlins | Devon Reed | SS | Milford (Del.) HS | Del. |
| 13 | 614 | Los Angeles Dodgers | Vince Spilker | RHP | Johnson County (Kan.) CC | Kan. |
| 14 | 615 | Los Angeles Angels | Junior Carlin | LHP | South Florida | Fla. |
| 15 | 616 | Oakland Athletics | Kurt Wunderlich | RHP | Michigan State | Mich. |
| 16 | 617 | Detroit Tigers | Tyler Barrett | LHP | Lewis-Clark State (Idaho) | Idaho |
| 17 | 618 | Colorado Rockies | Danny Winkler | RHP | Central Florida | Fla. |
| 18 | 619 | Toronto Blue Jays | Joel Seddon | RHP | St. Clair (Mich.) HS | Mich. |
| 19 | 620 | St. Louis Cardinals | Aramis Garcia | C | Pembroke Pines (Fla.) Charter HS | Fla. |
| 20 | 621 | Chicago White Sox | Martin Medina | C | Cal State Bakersfield | Calif. |
| 21 | 622 | Boston Red Sox | Zach Good | LHP | Grayson County (Texas) CC | Texas |
| 22 | 623 | San Diego Padres | Chris Haney | RHP | Dallas Baptist | Texas |
| 23 | 624 | Texas Rangers | Nick Vickerson | SS | Mississippi State | Miss. |
| 24 | 625 | Cincinnati Reds | Dan Jensen | RHP | Cincinnati | Ohio |
| 25 | 626 | Atlanta Braves | Carlos Rodriguez | LHP | Iolani HS, Honolulu | Hawaii |
| 26 | 627 | San Francisco Giants | Mitchell Beacom | LHP | UCLA | Calif. |
| 27 | 628 | Minnesota Twins | Brian Anderson | SS | Deer Creek HS, Edmond, Okla. | Okla. |
| 28 | 629 | New York Yankees | Daniel Camarena | LHP | Cathedral Catholic HS, San Diego | Calif. |
| 29 | 630 | Tampa Bay Rays | Garret Smith | SS | Boston College | Mass. |
| 30 | 631 | Philadelphia Phillies | Peter Lavin | OF | San Francisco | Calif. |