| Pick | Overall | Team | Player | Position | School | State |
| 1 | 806 | Washington Nationals | Sean Hoelscher | RHP | Texas A&M-Corpus Christi | Texas |
| 2 | 807 | Pittsburgh Pirates | Kevin Kleis | RHP | Grossmont (Calif.) JC | Calif. |
| 3 | 808 | Baltimore Orioles | Austin Urban | RHP | Richland HS, Johnstown, Pa. | Pa. |
| 4 | 809 | Kansas City Royals | Jose Rodriguez | OF | Miami Dade CC | Fla. |
| 5 | 810 | Cleveland Indians | Jeff Schaus | OF | Clemson | S.C. |
| 6 | 811 | Arizona Diamondbacks | Niko Gallego | 2B | UCLA | Calif. |
| 7 | 812 | New York Mets | Todd Weldon | RHP | Wayland Baptist (Texas) | Texas |
| 8 | 813 | Houston Astros | Jacke Healey | SS | Youngstown State | Ohio |
| 9 | 814 | San Diego Padres | Matt Branham | RHP | South Carolina-Upstate | S.C. |
| 10 | 815 | Oakland Athletics | Seth Frankoff | RHP | UNC Wilmington | N.C. |
| 11 | 816 | Toronto Blue Jays | Eric Arce | C | Lakeland (Fla.) HS | Fla. |
| 12 | 817 | Cincinnati Reds | Joel Bender | LHP | Oak Hills HS, Cincinnati | Ohio |
| 13 | 818 | Chicago White Sox | Pete Gehle | LHP | Azusa Pacific (Calif.) | Calif. |
| 14 | 819 | Milwaukee Brewers | Alex Jones | RHP | Jacksonville State | Ala. |
| 15 | 820 | Chicago Cubs | Bryan Harper | LHP | JC of Southern Nevada | Nev. |
| 16 | 821 | Tampa Bay Rays | Chris Winder | OF | Odessa (Texas) JC | Texas |
| 17 | 822 | Seattle Mariners | Nick Fleece | RHP | Texas A&M | Texas |
| 18 | 823 | Detroit Tigers | Les Smith | OF | Meramec (Mo.) CC | Mo. |
| 19 | 824 | Atlanta Braves | Willie Kempf | RHP | Baylor | Texas |
| 20 | 825 | Minnesota Twins | Brandon Henderson | OF | Fresno CC | Calif. |
| 21 | 826 | Texas Rangers | Alexander Claudio | LHP | Isabel Flores HS, Juncos, P.R. | P.R. |
| 22 | 827 | Florida Marlins | Brandon Cunniff | RHP | Cal State San Bernardino | Calif. |
| 23 | 828 | San Francisco Giants | Eric Sim | C | South Florida | Fla. |
| 24 | 829 | St. Louis Cardinals | Aiden Lucas | RHP | Denison (Ohio) | Ohio |
| 25 | 830 | Colorado Rockies | Blake Keitzman | LHP | Western Oregon | Ore. |
| 26 | 831 | Philadelphia Phillies | Matt Payton | 2B | Western Kentucky | Ky. |
| 27 | 832 | Los Angeles Dodgers | Yimy Rodriguez | RHP | Peru State (Neb.) | Neb. |
| 28 | 833 | Boston Red Sox | Jay Gonzalez | OF | Freedom HS, Orlando | Fla. |
| 29 | 834 | Los Angeles Angels | Brandon Decker | OF | Valdosta State (Ga.) | Ga. |
| 30 | 835 | New York Yankees | Martin Viramontes | RHP | Loyola Marymount | Calif. |