| Pick | Overall | Team | Player | Position | School | State |
| 1 | 232 | Washington Nationals | Roberto Perez | SS | Dorado Academy, Dorado, P.R. | P.R. |
| 2 | 233 | Seattle Mariners | Jimmy Gillheeney | LHP | North Carolina State | N.C. |
| 3 | 234 | San Diego Padres | Nate Freiman | 1B | Duke | N.C. |
| 4 | 235 | Pittsburgh Pirates | Colton Cain | LHP | Waxahachie (Texas) HS | Texas |
| 5 | 236 | Baltimore Orioles | Devin Harris | OF | East Carolina | N.C. |
| 6 | 237 | San Francisco Giants | Gus Benusa | OF | Riverview HS, Oakmont, Pa. | Pa. |
| 7 | 238 | Atlanta Braves | Kyle Rose | OF | Northwest Shoals (Ala.) CC | Ala. |
| 8 | 239 | Cincinnati Reds | Juan Silva | OF | Puerto Rico Baseball Academy, Gurabo, P.R. | P.R. |
| 9 | 240 | Detroit Tigers | Craig Fritsch | RHP | Baylor | Texas |
| 10 | 241 | Colorado Rockies | Rob Scahill | RHP | Bradley | Ill. |
| 11 | 242 | Kansas City Royals | Dusty Odenbach | RHP | Connecticut | Conn. |
| 12 | 243 | Oakland Athletics | Rob Gilliam | RHP | UNC Greensboro | N.C. |
| 13 | 244 | Texas Rangers | Braden Tullis | RHP | Skagit Valley (Wash.) CC | Wash. |
| 14 | 245 | Cleveland Indians | Cory Burns | RHP | Arizona | Ariz. |
| 15 | 246 | Arizona Diamondbacks | Paul Goldschmidt | 1B | Texas State | Texas |
| 16 | 247 | Los Angeles Dodgers | Jonathan Garcia | OF | Luis Munoz Marin HS, Yauco, P.R. | P.R. |
| 17 | 248 | Florida Marlins | Stephen Richards | LHP | Arkansas | Ark. |
| 18 | 249 | St. Louis Cardinals | Jason Stidham | SS | Florida State | Fla. |
| 19 | 250 | Toronto Blue Jays | Brian Slover | RHP | Cal State Northridge | Calif. |
| 20 | 251 | Houston Astros | Brandt Walker | RHP | Stanford | Calif. |
| 21 | 252 | Minnesota Twins | Brian Dozier | SS | Southern Mississippi | Miss. |
| 22 | 253 | Chicago White Sox | Ryan Buch | RHP | Monmouth | N.J. |
| 23 | 254 | New York Mets | Taylor Freeman | C | McNeese State | La. |
| 24 | 255 | New York Yankees | Sam Elam | LHP | Notre Dame | Ind. |
| 25 | 256 | Milwaukee Brewers | Chad Stang | OF | Midland (Texas) CC | Texas |
| 26 | 257 | Philadelphia Phillies | Jonathan Singleton | 1B | Millikan HS, Long Beach | Calif. |
| 27 | 258 | Boston Red Sox | Shannon Wilkerson | OF | Augusta State (Ga.) | Ga. |
| 28 | 259 | Tampa Bay Rays | Brett Nommensen | OF | Eastern Illinois | Ill. |
| 29 | 260 | Chicago Cubs | Robert Whitenack | RHP | SUNY Old Westbury | N.Y. |
| 30 | 261 | Los Angeles Angels | Carlos Ramirez | C | Arizona State | Ariz. |